hantzsch reaction using [mesi]cl as a new, efficient and bail catalyst
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abstract
in this work, the efficiency, generality and applicability of new bronsted acidic ionic liquid (bail) 1-methyl-3-(2-(sulfooxy)ethyl)-1h-imidazol-3-ium chloride {[msei]cl} as heterogeneous and green catalyst for organic transformations are studied. herein, the following one-pot multi-component reactions in the presence of [msei]cl are investigated: (i) the synthesis of quinoxaline derivatives from the reaction of phenylenediamines and 1,2-diketones in etoh under mild conditions (room temper-ature), (ii) the preparation of 1,4-dihydropyridines from one-pot multi component condensation of 1,3-dicarbonyl compounds, nh4oacand aldehydes under solvent-free conditions at moderate temperature (90 °c). high yields, relatively short reaction times, efficiency, generality, clean process, simple methodology, low cost, easy work-up, ease of preparation and regeneration of the catalyst and green conditions (in the synthesis of the quinoxaline derivatives) are advantages of the application of [mesi]cl as catalyst in the above organic reactions.
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Journal title:
iranian chemical communicationPublisher: payame noor university (pnu)
ISSN 2423-4958
volume 1
issue Issue 1 (pp. 1-82) 2013
Keywords
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